Freshman Kaho Nikaidou is from an influential family, and as such, no one has ever said anything even remotely mean to her, for fear of incurring her household's wrath. Wishing to be around people who will not treat her as special because of her background, she leaves home to live at a dormitory for her new school year. Shortly after arriving, Kaho accidentally wanders into traffic and is saved by a tall, handsome stranger. When she asks for his name, he tells her she is weird and walks away. Having finally met the only person to ever say an unkind word to her, Kaho falls head over heels for her savior. After meeting her rescuer yet again and discovering that his name is Kanade Takahashi, she confesses her love to him. Kanade says he would like for them to be a couple, but that Kaho may not want to date him after she finds out his secret. To her shock, Kaho discovers the startling truth: Kanade is a fifth grader! Deciding that she can't date a fifth grader, Kaho intends to break up with him. But as she spends more time with Kanade, she begins to care for him even more and continues dating him. Hatsukoi Monster follows Kaho's first steps into love with Kanade, her immature, yet kind, fifth grade boyfriend.

In 2008, the Japanese government began hunting people who identify as otaku in an effort to protect the country's culture. In just one week, the enforcement agency known as the SSC captured almost every otaku by force and confiscated their memorabilia. One passionate man calling himself Otaku Hero refuses to allow this agency to do as they please: he raises a resistance army made up of other displaced geeks who band together to help defend their culture. Three years later, the fires of rebellion wane as all hope seems lost for otakus. Spurred on by his ally—the magical girl Anarchy—Otaku Hero commands the resistance in an effort to reunite Anarchy with the other two other magical girls: Blue and Pink. By combining the power of this trio, the resistance may be able to defeat the SSC and save otaku culture for everyone.

The Daihasei Festival has begun, and that of course means that Tokiwadai Middle School—a prestigious all-girls' middle school—is competing too. Despite the participation of the "Ace of Tokiwadai," Mikoto Misaka, the other students who are participating are still putting their utmost effort into winning, no matter how impossible the feat may seem against her might. However, not all is fun and games. Due to the the festival, Academy City opens to the outside world, and various factions have begun plotting ways to infiltrate the city. Misaka appears to be on their radar, and as the festival proceeds, people lurking from the shadows begin to emerge... Toaru Kagaku no Railgun T brings back the Tokiwadai Ace and her friends as they dive deeper into the dark side of Academy City. From terrorist attacks to ruthless underground projects, anything is possible in this city. [Written by MAL Rewrite]

Specials included in the Blu-ray and DVD releases.